CHEMISTRY: Resisting Dendrimers

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Dendrimers and supramolecular chemistry.

S ince their introduction in 1985 by Tomalia et al. (1) and Newkome et al. (2), dendrimers have attracted much attention because of their fascinating structure and unique properties (3, 4). Dendrimers are globular, size monodisperse macromolecules in which all bonds emerge radially from a central focal point or core with a regular branching pattern and with repeat units that each contribute a b...

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Multivalent, bifunctional dendrimers prepared by click chemistry.

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Organophosphorus chemistry for the synthesis of dendrimers.

Dendrimers are multifunctional, hyperbranched and perfectly defined macromolecules, synthesized layer after layer in an iterative manner. Besides the nature of the terminal groups responsible for most of the properties, the nature of the internal structure, and more precisely of the branching points, is also of crucial importance. For more than 15 years, we have demonstrated that the presence o...

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ژورنال

عنوان ژورنال: Science

سال: 2004

ISSN: 0036-8075,1095-9203

DOI: 10.1126/science.304.5671.651e